﻿<?xml version="1.0" encoding="utf-8"?>
<lesson name="SCAA2_1" width="900" height="600" version="15">
 <runOptions mode="1" startLessonNodeID="-1" startElementID="-1" />
 <lessonPreference passmark="100" repeat="False" isTimeoutEnabled="False" timeout="0">
  <webResult webResultUrl="" webFields="0000000" sendWebResult="False" />
  <qcNode qcUrl="http://microcraft.org/bt/edit_bug.aspx" qcKey="0" />
  <loginNode requireLogin="False" length="0" validation="0" prompt=""><![CDATA[]]></loginNode>
 </lessonPreference>
 <userVariables count="8">
  <variable id="1000" name="PlayMusic" type="1" bookMark="False" />
  <variable id="1001" name="MenuAudio" type="1" bookMark="False" />
  <variable id="1002" name="16_1" type="1" bookMark="False" />
  <variable id="1003" name="16_2" type="1" bookMark="False" />
  <variable id="1004" name="s7_1_ans" type="1" bookMark="False" />
  <variable id="1005" name="s7_2_ans" type="1" bookMark="False" />
  <variable id="1006" name="s7_3_ans" type="1" bookMark="False" />
  <variable id="1007" name="s7_4_ans" type="1" bookMark="False" />
 </userVariables>
 <lessonInfo>
  <titleImage></titleImage>
  <titleImageDelay></titleImageDelay>
  <useFrame>True</useFrame>
  <lessonFrame>none</lessonFrame>
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    <removeActions>False</removeActions>
    <background-color>#000000</background-color>
    <image>unit 2.jpg</image>
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    <barImage>ProgressBar-863.png</barImage>
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    <textMoveY>0</textMoveY>
    <imageMoveXMouseOver>0</imageMoveXMouseOver>
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    <textMoveXMouseOver>0</textMoveXMouseOver>
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    <imageX>0</imageX>
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    <normalTextColor>#120000</normalTextColor>
    <normalBackgroundColor>transparent</normalBackgroundColor>
    <normalStartColor>#FFFFFF</normalStartColor>
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    <normalBackgroundColorMouseOver>transparent</normalBackgroundColorMouseOver>
    <normalStartColorMouseOver>#FFFFFF</normalStartColorMouseOver>
    <normalEndColorMouseOver>#9EBDCF</normalEndColorMouseOver>
    <normalImageMouseOver width="61" height="62">button back mo.png</normalImageMouseOver>
    <normalTextColorMouseDown>#000000</normalTextColorMouseDown>
    <normalBackgroundColorMouseDown>transparent</normalBackgroundColorMouseDown>
    <normalStartColorMouseDown>#DBFBFF</normalStartColorMouseDown>
    <normalEndColorMouseDown>#8DB9D1</normalEndColorMouseDown>
    <normalImageMouseDown width="61" height="62">button back.png</normalImageMouseDown>
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    <toggledBackgroundColor>transparent</toggledBackgroundColor>
    <toggledStartColor>#FFFFFF</toggledStartColor>
    <toggledEndColor>#FFFFFF</toggledEndColor>
    <toggledImage width="0" height="0" />
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    <toggledBackgroundColorMouseOver>transparent</toggledBackgroundColorMouseOver>
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    <toggledImageMouseDown width="0" height="0" />
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    <markedBackgroundColorMouseOver>transparent</markedBackgroundColorMouseOver>
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    <markedImageMouseOver width="61" height="62">button back mo.png</markedImageMouseOver>
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    <markedEndColorMouseDown>#FFFFFF</markedEndColorMouseDown>
    <markedImageMouseDown width="61" height="62">button back.png</markedImageMouseDown>
    <pictureBoxWidth>61</pictureBoxWidth>
    <pictureBoxHeight>62</pictureBoxHeight>
    <isToggledButton>False</isToggledButton>
    <resetNamePrefix />
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    <navigationAction>1</navigationAction>
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    <markOptionComplete>False</markOptionComplete>
    <name>Back</name>
    <value>Back</value>
    <key1 />
    <key2 />
    <tooltips />
    <cursor>0</cursor>
    <isRespondToClick>True</isRespondToClick>
    <isRespondToMouseOver>False</isRespondToMouseOver>
    <valueOnMouseOver />
    <isRespondToMouseLeave>False</isRespondToMouseLeave>
    <valueOnMouseLeave />
    <valueOnShiftClick />
    <valueOnCtrlClick />
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   <action type="CUSTOMBUTTON" id="2" name="Next" hasCondition="False">
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    <key2 />
    <tooltips />
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    <valueOnMouseOver />
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    <valueOnMouseLeave />
    <valueOnShiftClick />
    <valueOnCtrlClick />
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    <normalBackgroundColor>transparent</normalBackgroundColor>
    <normalStartColor>#FFFFFF</normalStartColor>
    <normalEndColor>#A9A9A9</normalEndColor>
    <normalImage width="61" height="62">button menu.png</normalImage>
    <normalTextColorMouseOver>#120000</normalTextColorMouseOver>
    <normalBackgroundColorMouseOver>transparent</normalBackgroundColorMouseOver>
    <normalStartColorMouseOver>#FFFFFF</normalStartColorMouseOver>
    <normalEndColorMouseOver>#9EBDCF</normalEndColorMouseOver>
    <normalImageMouseOver width="61" height="62">button menu mo.png</normalImageMouseOver>
    <normalTextColorMouseDown>#000000</normalTextColorMouseDown>
    <normalBackgroundColorMouseDown>transparent</normalBackgroundColorMouseDown>
    <normalStartColorMouseDown>#DBFBFF</normalStartColorMouseDown>
    <normalEndColorMouseDown>#8DB9D1</normalEndColorMouseDown>
    <normalImageMouseDown width="61" height="62">button menu.png</normalImageMouseDown>
    <toggledTextColor>#000000</toggledTextColor>
    <toggledBackgroundColor>transparent</toggledBackgroundColor>
    <toggledStartColor>#FFFFFF</toggledStartColor>
    <toggledEndColor>#FFFFFF</toggledEndColor>
    <toggledImage width="0" height="0" />
    <toggledTextColorMouseOver>#000000</toggledTextColorMouseOver>
    <toggledBackgroundColorMouseOver>transparent</toggledBackgroundColorMouseOver>
    <toggledStartColorMouseOver>#FFFFFF</toggledStartColorMouseOver>
    <toggledEndColorMouseOver>#FFFFFF</toggledEndColorMouseOver>
    <toggledImageMouseOver width="0" height="0" />
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    <toggledBackgroundColorMouseDown>transparent</toggledBackgroundColorMouseDown>
    <toggledStartColorMouseDown>#FFFFFF</toggledStartColorMouseDown>
    <toggledEndColorMouseDown>#FFFFFF</toggledEndColorMouseDown>
    <toggledImageMouseDown width="0" height="0" />
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    <markedBackgroundColor>transparent</markedBackgroundColor>
    <markedStartColor>#FFFFFF</markedStartColor>
    <markedEndColor>#FFFFFF</markedEndColor>
    <markedImage width="0" height="0" />
    <markedTextColorMouseOver>#D3D3D3</markedTextColorMouseOver>
    <markedBackgroundColorMouseOver>transparent</markedBackgroundColorMouseOver>
    <markedStartColorMouseOver>#FFFFFF</markedStartColorMouseOver>
    <markedEndColorMouseOver>#FFFFFF</markedEndColorMouseOver>
    <markedImageMouseOver width="61" height="62">button menu mo.png</markedImageMouseOver>
    <markedTextColorMouseDown>#D3D3D3</markedTextColorMouseDown>
    <markedBackgroundColorMouseDown>transparent</markedBackgroundColorMouseDown>
    <markedStartColorMouseDown>#FFFFFF</markedStartColorMouseDown>
    <markedEndColorMouseDown>#FFFFFF</markedEndColorMouseDown>
    <markedImageMouseDown width="61" height="62">button menu.png</markedImageMouseDown>
    <pictureBoxWidth>61</pictureBoxWidth>
    <pictureBoxHeight>62</pictureBoxHeight>
    <isToggledButton>False</isToggledButton>
    <resetNamePrefix />
    <buttonType>2</buttonType>
    <navigationAction>4</navigationAction>
    <menuOptionID>0</menuOptionID>
    <markOptionComplete>False</markOptionComplete>
    <name>ToMainMenu</name>
    <value>ToMainMenu</value>
    <key1 />
    <key2 />
    <tooltips />
    <cursor>0</cursor>
    <isRespondToClick>True</isRespondToClick>
    <isRespondToMouseOver>False</isRespondToMouseOver>
    <valueOnMouseOver />
    <isRespondToMouseLeave>False</isRespondToMouseLeave>
    <valueOnMouseLeave />
    <valueOnShiftClick />
    <valueOnCtrlClick />
   </action>
  </list>
 </lessonRoot>
 <lessonNode id="1" type="MENU" parent="0" name="Main Menu" showInReference="True" showIntroductionOnce="True" showEndOnExitLesson="False" showEndOnCompletion="False" showEndOnGoBack="False">
  <list type="INTRODUCTION" id="1-1" show="ALL">
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     <text><![CDATA[We often describe solutions in terms of one substance dissolving another - the solute dissolves in the solvent.]]></text>
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     <text><![CDATA[Usually there is much more solvent than solute and the solubility of a substance is the maximum amount that can dissolve in a fixed amount of solvent to form a stable solution at a specified temperature. ]]></text>
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     <text><![CDATA[Concentration is the amount of solute dissolved in a solution and expressed in terms of how much substance is present in a given mass or volume of the solution.]]></text>
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     <text><![CDATA[The table below shows some terms used to define concentration:]]></text>
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     <text><![CDATA[However, in most situations relating to film formers, the substances are miscible in any proportion with the solvent and the term solvent simply refers to the fact that it will evaporate after application and leave the film former behind. ]]></text>
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     <text><![CDATA[Concentration is simply a measure of the amount of film forming solids present in the solution.]]></text>
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     <text><![CDATA[The 'ideal' surface coating is 100% solids and contains no solvent. ]]></text>
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     <text><![CDATA[We've had numerous examples of this in our lessons so far as well as the instance of a polymerisable solvent, styrene, crosslinking with the film former in unsaturated polyester gelcoats. Later on, we'll study powder coatings.]]></text>
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     <text><![CDATA[In general, however, solvents dissolve resins and polymers to form solutions. These solutions allow simplified manufacture and application of paints and, as a result of solvent evaporation, facilitate the formation of the paint film. ]]></text>
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     <text><![CDATA[In essence, solvents convert aggregates of resin and polymer molecules into single molecules or small clusters of molecules in solution. ]]></text>
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     <text><![CDATA[In a solution, molecules of solute and solvent are dispersed one within the other.]]></text>
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     <text><![CDATA[Forming a solution]]></text>
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     <text><![CDATA[Forming a solution is simply a process of separating molecules although, as we've seen previously, the higher the molecular weight of the resin or polymer, the more difficult it is to dissolve. ]]></text>
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     <text><![CDATA[As the solvent evaporates after application of the paint, the resin or polymer molecules reform aggregates and become solid. ]]></text>
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     <text><![CDATA[Again, the high molecular weight polymers, which were difficult to dissolve, may now become slow to release the solvent.]]></text>
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     <text><![CDATA[Read Surface Coatings Vol 1, section 24.1]]></text>
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   <correctAnswer><![CDATA[]]></correctAnswer>
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     <text><![CDATA[Please write down what you understand by the terms soluble and miscible. Compare your answers with those on the next screen.]]></text>
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     <text><![CDATA[Soluble:]]></text>
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<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:13pt;">&nbsp;</span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:13pt;">A substance (the solute) is said to be </span><span style="font-family:'Trebuchet MS';font-size:14pt;"><b>soluble</b></span><span style="font-family:'Trebuchet MS';font-size:13pt;"> in a solvent if it can be dissolved. At any given temperature there is a maximum amount of solute which can dissolve in a fixed volume of solvent. </span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:13pt;">&nbsp;</span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:13pt;">&nbsp;</span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:13pt;">When there is no maximum amount of solute then the substance is </span><span style="font-family:'Trebuchet MS';font-size:14pt;"><b>miscible</b></span><span style="font-family:'Trebuchet MS';font-size:13pt;"><b> </b></span><span style="font-family:'Trebuchet MS';font-size:13pt;">with the solvent. All gases are miscible with one another. &nbsp;</span></p></body>]]></html>
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     <text><![CDATA[We often describe solutions in terms of one substance dissolving another - the solute dissolves in the solvent.]]></text>
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     <text><![CDATA[Usually there is much more solvent than solute and the solubility of a substance is the maximum amount that can dissolve in a fixed amount of solvent to form a stable solution at a specified temperature.]]></text>
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     <text><![CDATA[Concentration is the amount of solute dissolved in a solution and expressed in terms of how much substance is present in a given mass or volume of the solution.]]></text>
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     <text><![CDATA[However, in most situations relating to film formers, the substances are miscible in any proportion with the solvent and the term solvent simply refers to the fact that it will evaporate after application and leave the film former behind. ]]></text>
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     <text><![CDATA[Concentration is simply a measure of the amount of film forming solids present in the solution.]]></text>
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     <text><![CDATA[2.1.2  Solvents, Diluents and Thinners]]></text>
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     <text><![CDATA[Types of solvent ]]></text>
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     <text><![CDATA[With the notable exception of water, all solvents, thinners and diluents used in surface coatings are organic compounds of low molecular weight. ]]></text>
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     <text><![CDATA[Whilst a solvent dissolves the binder in a paint, diluents and thinners may be added to reduce the viscosity to meet application requirements and also to lower the cost of a true solvent. ]]></text>
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     <text><![CDATA[It is unusual for a single solvent to be used in a surface coating, not only for reasons of cost but to give balance to other characteristics such as evaporation rate and flow.]]></text>
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     <text><![CDATA[Up to now we've been largely concerned with the use of solvents or solvent mixtures that dissolve the binder.]]></text>
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     <text><![CDATA[There is a growing class of binders that are not in solution, but nevertheless require the use of a diluent, which is a non-solvent for the binder, for application.]]></text>
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     <text><![CDATA[Water is thus a diluent for aqueous latex paints, and aliphatic hydrocarbons are examples of diluents for some non-aqueous polymer dispersions or NADs. ]]></text>
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     <text><![CDATA[These dispersions usually require a latent solvent or coalescing agent (solvent) to ensure that the dispersed particles coalesce to form a continuous film on evaporation of the diluent.]]></text>
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   <correctAnswer><![CDATA[]]></correctAnswer>
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     <text><![CDATA[Self-assessment]]></text>
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     <text><![CDATA[Please write your answers to the questions on your screen and compare your work with the answers that follow on the next screen.]]></text>
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     <text><![CDATA[1) What is the role of a latent solvent?]]></text>
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     <text><![CDATA[2) How would you describe water in a latex based paint?]]></text>
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     <text><![CDATA[3) Is a thinner the same as a true solvent?]]></text>
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     <text><![CDATA[4) What is a coalescing agent?]]></text>
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     <text><![CDATA[Please type in your answers then click Next.]]></text>
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     <text><![CDATA[[s7_4_ans]]]></text>
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     <text><![CDATA[Model answers:]]></text>
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     <text><![CDATA[1) A latent solvent enhances the solvent      power of a true solvent but cannot           dissolve the film former on its own.]]></text>
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     <text><![CDATA[2) Water is diluent in a latex based paint.]]></text>
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     <text><![CDATA[3) A thinner is generally a solvent blend       designed to reduce the viscosity of a       surface coating to suit application]]></text>
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     <text><![CDATA[4) A coalescing agent is a <br/>    solvent, often present in a <br/>    latex or NAD, which assists<br/>    in the coalescing of the <br/>    binder particles.]]></text>
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     <text><![CDATA[Whilst a solvent dissolves the binder in a paint, diluents and thinners may be added to reduce the viscosity to meet application requirements and also to lower the cost of a true solvent. ]]></text>
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     <text><![CDATA[It is unusual for a single solvent to be used in a surface coating, not only for reasons of cost but to give balance to other characteristics such as evaporation rate and flow.]]></text>
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     <text><![CDATA[There are four types of solvent used according to their behavior. ]]></text>
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     <text><![CDATA[They are true or active solvents, latent solvents, diluents and thinners. Thinners are often a blend of the first three.]]></text>
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     <text><![CDATA[2.1.3  Solvent Types]]></text>
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     <text><![CDATA[Hydrocarbon solvents]]></text>
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     <text><![CDATA[There are two main types of organic solvent used in coatings, hydrocarbons and oxygenated compounds which are covered later in this section. ]]></text>
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     <text><![CDATA[Hydrocarbon solvents contain only carbon and hydrogen, and the main structural groups are shown below.]]></text>
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     <text><![CDATA[White spirit is a branched (mixed) paraffin and aromatic fractions include toluene, xylene, Solvesso (Exxon) and Shellsol A (Shell) grades.]]></text>
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     <text><![CDATA[Properties of hydrocarbon solvents]]></text>
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     <text><![CDATA[The properties of hydrocarbon solvents are dictated by two factors: their carbon numbers or molecular weights and the type of hydrocarbons they contain.]]></text>
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     <text><![CDATA[The table below compares some properties of the different types of hydrocarbons at the same carbon number.]]></text>
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     <text><![CDATA[For example, boiling point increases as you go from paraffin to naphthene to aromatics.  However, molecular weight decreases as you go from paraffin to naphthene to aromatic.]]></text>
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     <text><![CDATA[In general there is a steady progression from paraffin through naphthenes to aromatics but hydrocarbons have low to medium solvency and dissolve only some of the resins, such as alkyds, used in surface coatings.]]></text>
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     <text><![CDATA[Oxygenated solvents]]></text>
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     <text><![CDATA[Oxygenated solvents contain oxygen in addition to carbon and hydrogen. ]]></text>
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     <text><![CDATA[The manner in which oxygen is bound within the molecule determines the physical and chemical properties of the solvent and hence its classification.]]></text>
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     <text><![CDATA[A wide range of oxygenated solvents is used in coatings, including ketones, esters, alcohols, glycol ethers and glycol ether acetates.]]></text>
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     <text><![CDATA[The properties of oxygenated solvents vary with their classification. Ketones, for instance, will dissolve vinyl resins, whereas alcohols will not. The chemical structure of the solvents affects their physical properties.]]></text>
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     <text><![CDATA[Alcohols are strongly hydrogen-bonded and have lower vapour pressure than other types of oxygenated solvents with similar boiling points. Methyl ethyl ketone and isopropanol show this effect. ]]></text>
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]]></html>
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     <text><![CDATA[Oxygenated solvents in general are more powerful solvents than hydrocarbons and are mostly used in industrial coatings. They have strong odours, although not always unpleasant, and are generally more expensive than hydrocarbons.]]></text>
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     <text><![CDATA[Read Surface Coatings Vol 1, sections 24.2.1 and 2]]></text>
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   <correctAnswer><![CDATA[A|E]]></correctAnswer>
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     <text><![CDATA[Self-assessment]]></text>
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     <text><![CDATA[Which of the following statements are true?]]></text>
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     <text><![CDATA[Please click on the correct buttons and then click Next.]]></text>
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     <text><![CDATA[Oxygenated solvents are generally stronger than hydrocarbons<br/>]]></text>
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     <text><![CDATA[White spirit is a linear paraffin<br/>]]></text>
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     <text><![CDATA[Evaporation rate is directly related to the boiling point of a solvent<br/>]]></text>
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     <text><![CDATA[Aromatic hydrocarbons have a stronger odour than oxygenated solvents<br/>]]></text>
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     <text><![CDATA[Paraffins have a higher molecular weight than aromatic hydrocarbons at the same carbon number ]]></text>
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      <text><![CDATA[Incorrect. <br/> <br/>There are two correct answers. <br/><br/>Please try again.]]></text>
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      <text><![CDATA[Incorrect.<br/><br/>The correct answers are displayed. White spirit is a branched paraffin. <br/><br/>MEK and Isopropanol have similar boiling points but MEK has twice the evaporation rate.<br/><br/>Oxygenated solvents generally have stronger odour than hydrocarbons.<br/>]]></text>
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     <text><![CDATA[There are two main types of solvent, hydrocarbons and oxygenated compounds.]]></text>
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     <text><![CDATA[In general there is a steady progression from paraffin through naphthenes to aromatics but hydrocarbons have low to medium solvency and dissolve only some of the resins, such as alkyds, used in surface coatings.]]></text>
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     <text><![CDATA[For example, boiling point increases as you go from paraffin to naphthene to aromatics. ]]></text>
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     <text><![CDATA[However, molecular weight decreases as you go from paraffin to naphthene to aromatic.]]></text>
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     <text><![CDATA[Oxygenated solvents contain oxygen in addition to carbon and hydrogen. The manner in which oxygen is bound within the molecule determines the physical and chemical properties of the solvent and hence its classification.]]></text>
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     <text><![CDATA[Oxygenated solvents in general are more powerful solvents than hydrocarbons and are mostly used in industrial coatings. ]]></text>
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     <text><![CDATA[The KB value of a solvent represents the maximum amount of hydrocarbon solvent that can be added to a stock solution of kauri resin in butyl alcohol without causing cloudiness.]]></text>
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     <text><![CDATA[Kauri resin is readily soluble in butyl alcohol but not in hydrocarbon solvents and the resin solution will tolerate only a certain amount of dilution.]]></text>
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     <text><![CDATA[Aromatic hydrocarbon solvents such as toluene can be added in greater amount, with a value of around 100 compared with weak aliphatic hydrocarbons with a value of 20.]]></text>
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     <text><![CDATA[The flash point of a solvent or solvent mixture is important to those concerned in the manufacture, handling, storage, transport and use of solvent-containing products. ]]></text>
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     <text><![CDATA[The flash point of a liquid may be defined as the lowest temperature at which the liquid, in contact with air, is capable of being ignited by a spark or flame under specified conditions.]]></text>
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     <text><![CDATA[Two methods of determining flash point are in common use, either by open cup or closed cup.]]></text>
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     <text><![CDATA[In each case the sample is heated and stirred and the temperature recorded when a flash occurs. Originally, results were quoted by the name of the instrument, e.g. Abel (open cup) or Pensky-Marten (closed cup), but there are now many instruments available and a considerable number of specifications covering their use.]]></text>
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     <text><![CDATA[Boiling points and flash points of some common solvents]]></text>
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     <text><![CDATA[It should not be assumed that a mixture of solvents will have the flashpoint of the solvent with the lowest flashpoint as sometimes a lower flashpoint for the mixture may be obtained experimentally.]]></text>
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     <text><![CDATA[Dependence of vapour pressure upon temperature]]></text>
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     <text><![CDATA[A gas which is easily condensed to a liquid is called a vapour. ]]></text>
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     <text><![CDATA[If a liquid is placed in a closed container it will vapourise until it reaches an equilibrium between liquid and vapour. ]]></text>
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     <text><![CDATA[The maximum pressure generated is its saturated vapour pressure at the temperature in question.]]></text>
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     <text><![CDATA[The surface tension of a solvent is a measure of how well it will wet a surface and it is also a measure of its capillarity or capillary action. ]]></text>
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     <text><![CDATA[Water has a high surface tension which means it has poor wetting action especially towards hydrophobic surfaces e.g. metal surfaces that may have slight oily contamination or some plastics.]]></text>
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     <text><![CDATA[On the other hand, high surface tension also gives rise to a strong capillary action so that water penetrates absorbent surfaces, hence the familiar removal of water by a towel. This phenomenon also contributes to the loss of water from latex dispersions on drying as we've already seen.]]></text>
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     <text><![CDATA[Although there are instruments for measuring the surface tension of liquids, the visual inspection of wetting by the thinned and applied coating is just as important. ]]></text>
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     <text><![CDATA[Surfaces to be coated, depending also on any pre-treatment, can vary greatly in their acceptance of film formers, solvents and thinners.]]></text>
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     <text><![CDATA[Contaminants are unlikely to be encountered when solvents are purchased from suppliers with quality assurance programmes and the product can be certified according to international standards.]]></text>
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     <text><![CDATA[For polyurethanes, solvents should be free of water or alcohols.]]></text>
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     <text><![CDATA[Oily residues, odour, colour or the presence of unsaturates are all indicative of contamination.]]></text>
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     <text><![CDATA[Measurements such as refractive index and density or specific gravity can be used to determine the identity of single component solvents but may not establish levels of impurities for which other tests will be necessary.]]></text>
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     <text><![CDATA[Read Surface Coatings Vol 1, sections 24.3.1.5, 24.3.2 and 24.5.1]]></text>
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   <correctAnswer><![CDATA[D]]></correctAnswer>
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     <text><![CDATA[Boiling point of a solvent is an indication of:]]></text>
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     <text><![CDATA[Please click on the correct button.]]></text>
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     <text><![CDATA[Evaporation rate<br/><br/><br/>Solvent purity<br/><br/><br/>Flash point<br/><br/><br/>All of the above]]></text>
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     <text><![CDATA[A Kauri Butanol value of 90 is likely to be]]></text>
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     <text><![CDATA[Please click on the correct button.]]></text>
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     <text><![CDATA[Methyl ethyl ketone <br/><br/><br/>White spirit<br/><br/><br/>Xylene<br/><br/><br/>Isopropanol]]></text>
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     <text><![CDATA[High surface tension of a solvent will give]]></text>
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     <text><![CDATA[Please click on the correct button.]]></text>
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     <text><![CDATA[Good surface wetting<br/><br/><br/>Penetration of porous surfaces<br/><br/><br/>Poor resin solubility<br/><br/><br/>Indication of contaminants<br/>]]></text>
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      <text><![CDATA[Incorrect.<br/><br/>Please try again.]]></text>
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      <text><![CDATA[Incorrect.<br/><br/>The correct answer is displayed.<br/><br/>High surface tension is associated with poor surface wetting but strong capillary action.]]></text>
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     <text><![CDATA[Considerations when selecting a solvent include: cost, solvent power, volatility, toxicity, odour, flammability/flash point, viscosity, colour, water content, surface tension, contaminants, environmental or legislative requirements.]]></text>
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     <text><![CDATA[Kauri Butanol value and Aniline Point are methods of assessing the comparative solvent power of hydrocarbon solvents.]]></text>
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     <text><![CDATA[2.1.5  Solvent Evaporation]]></text>
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     <text><![CDATA[Evaporation characteristics]]></text>
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     <text><![CDATA[So far, we've generally been looking at solvent properties individually but the largest use of solvents is in blends which are used in conjunction with film formers for surface coatings.]]></text>
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     <text><![CDATA[We can easily study the evaporation characteristics of solvents or diluents on their own but there are many other factors which will come into play when they are used as part of a paint formulation.]]></text>
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     <text><![CDATA[The relative evaporation rate of solvents or diluents can be determined by measuring their loss in weight or volume as a function of time.]]></text>
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     <text><![CDATA[However, there are several methods, ranging from the evaporation of a wet film on a metal dish to the visual disappearance of a fixed volume of solvent applied to a filter paper.]]></text>
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     <text><![CDATA[ASTM D3539-87(1996) is based on a thin film evaporometer developed by Shell Chemicals and uses n-butyl acetate = 1.0 as a comparative standard.]]></text>
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     <text><![CDATA[The German standard DIN 53170 uses diethyl ether = 1.0 as the value by which all other solvents are compared.]]></text>
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     <text><![CDATA[Evaporation rates of paint solvents          (average values)]]></text>
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     <text><![CDATA[Controlled rate of evaporation]]></text>
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     <text><![CDATA[It is common to use solvent blends so as to provide a controlled rate of evaporation from the paint film, for example a rapid initial release to allow film build without runs or sags followed by a slow evaporation to promote flow. ]]></text>
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     <text><![CDATA[We've previously discussed the use of latent solvents and diluents for cost reduction.]]></text>
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     <text><![CDATA[Interaction between solvents means that the mixture is non-ideal, so that the overall evaporation behavior cannot be predicted using only the concentrations and evaporation rates of the components. ]]></text>
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     <text><![CDATA[Controlled rate of evaporation]]></text>
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     <text><![CDATA[The evaporation rate of n-butanol, for example, is controlled by the high degree of hydrogen-bonding within the molecule. ]]></text>
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     <text><![CDATA[When n-butanol is blended with xylene, as is often the case in alkyd/melamine coatings, its evaporation rate increases. ]]></text>
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     <text><![CDATA[This is because the molecules of the alcohol are separated and dispersed among the molecules of xylene. ]]></text>
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     <text><![CDATA[The retarding effect of the hydrogen bonding in the alcohol is lessened and it evaporates more quickly.]]></text>
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     <text><![CDATA[Where blends are more complicated and the proportions of solvents change markedly during evaporation, as is often the case in practice, predicting evaporation rates requires an increasing number of assumptions with a corresponding decrease in accuracy.]]></text>
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     <text><![CDATA[When a solvent evaporates from a solution coating film, interactions between the resin and the solvent influence the evaporation rate. ]]></text>
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     <text><![CDATA[In the early stages of evaporation, when the film is essentially liquid and the solution is one of resin in solvent, the evaporation rate from the solution is similar to that of the solvent.]]></text>
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     <text><![CDATA[With a pure solvent the surface consists entirely of molecules that can vaporise. In a solution, some of the surface is occupied by the non-volatile solute molecules. Thus the fraction of the surface occupied by solvent molecules is smaller and the rate of vaporisation must be lower.]]></text>
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		<p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:12pt;font-weight:bold;font-style:normal;">This relationship is expressed by Raoult&rsquo;s Law:</span></p><p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Segoe UI';font-size:15pt;font-weight:normal;font-style:normal;">&nbsp;</span></p><p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">	</span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:16pt;font-weight:normal;font-style:italic;">P</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:10pt;font-weight:normal;font-style:normal;"><sub>solvent</sub></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> = </span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:16pt;font-weight:normal;font-style:italic;">X</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:10pt;font-weight:normal;font-style:normal;"><sub>solvent</sub></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> </span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:12pt;font-weight:normal;font-style:normal;">x</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> </span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:16pt;font-weight:normal;font-style:italic;">P</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:10pt;font-weight:normal;font-style:normal;"><sup>o</sup></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:10pt;font-weight:normal;font-style:normal;"><sub>solvent</sub></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> </span></p><p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Segoe UI';font-size:15pt;font-weight:normal;font-style:normal;">&nbsp;</span></p><p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:12pt;font-weight:bold;font-style:normal;">where</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> </span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:16pt;font-weight:normal;font-style:italic;">P</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:10pt;font-weight:normal;font-style:normal;"><sub>solvent</sub></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> </span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:12pt;font-weight:bold;font-style:normal;">is the vapour pressure of the solvent above the solution</span></p><p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:16pt;font-weight:normal;font-style:italic;">X</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:10pt;font-weight:normal;font-style:normal;"><sub>solvent </sub></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:12pt;font-weight:bold;font-style:normal;">is the mole fraction of the solvent in the solution</span></p><p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:16pt;font-weight:normal;font-style:italic;">P</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:10pt;font-weight:normal;font-style:normal;"><sup>o</sup></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet 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     <text><![CDATA[Towards the end of evaporation, when the solution is very highly viscous or solid and one of solvent in resin, the evaporation rate is controlled by diffusion of solvent molecules to the surface of the film.]]></text>
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     <text><![CDATA[At this stage the shape of the solvent ]]></text>
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     <text><![CDATA[molecules becomes more important than the chemical nature of solvent and resin.]]></text>
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     <text><![CDATA[Solvent release from resin/polymer films versus evaporation rates]]></text>
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     <text><![CDATA[There is no direct relationship between evaporation rate and solvent release. <br/>For example, n-heptane and 2,4-dimethyl pentane are both C7 hydrocarbons. The bulkier, branched 2,4-dimethyl pentane evaporates more than 1.5 times as fast as linear n-heptane yet is released from the polymer film much later.]]></text>
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     <text><![CDATA[If the thickness of the film is doubled the retention time is quadrupled.]]></text>
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     <text><![CDATA[Rate of evaporation]]></text>
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     <text><![CDATA[In any solvent blend it is important that the last trace of solvent to evaporate should be a true solvent in order to avoid precipitation of the resin and to relieve stress within the film.]]></text>
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     <text><![CDATA[A true solvent will be retained longer by a polymer film and may, indeed, act as a solvent plasticiser before finally evaporating.]]></text>
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     <text><![CDATA[Hard resins retain solvents longer than soft resin films. This effect is seen when heating polymers containing residual solvents above their glass transition temperatures. ]]></text>
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     <text><![CDATA[Solvent release just above the transition temperature is much faster than would be expected from the increase of temperature alone.]]></text>
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     <text><![CDATA[Rate of evaporation]]></text>
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     <text><![CDATA[Drying conditions will obviously affect the rate of evaporation of solvents. ]]></text>
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     <text><![CDATA[Increased temperature by way of convection or infra-red ovens will hasten evaporation as we've just noted. ]]></text>
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     <text><![CDATA[Read Surface Coatings Vol 1, section 24.3.1.2]]></text>
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   <correctAnswer><![CDATA[C|D|E]]></correctAnswer>
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     <text><![CDATA[Self-assessment]]></text>
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     <text><![CDATA[Which of the following statements are true? ]]></text>
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     <text><![CDATA[Please click on the correct buttons and then click Next.]]></text>
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     <text><![CDATA[n-Butyl alcohol is the standard for solvent evaporation rate in ASTM D3539]]></text>
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     <text><![CDATA[Solvent release from resin/polymer films is directly related to evaporation rate]]></text>
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     <text><![CDATA[Soft polymers release solvent more quickly than hard polymers]]></text>
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      <text><![CDATA[Correct.<br/><br/>]]></text>
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      <text><![CDATA[Incorrect. <br/><br/>There are three true statements. <br/>Please try again. ]]></text>
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      <text><![CDATA[Incorrect.<br/><br/>The true statements are displayed.<br/><br/>n-Butyl acetate is the standard for ASTM D3539. <br/><br/>Solvent release from polymeric films<br/>is a function of structure of the <br/>solvent molecules as well as evaporation rate.]]></text>
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     <text><![CDATA[The relative evaporation rate of solvents or diluents can be determined by measuring their loss in weight or volume as a function of time.]]></text>
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     <text><![CDATA[Towards the end of evaporation, when the solution is very highly viscous or solid and one of solvent in resin, the evaporation rate is controlled by diffusion of solvent molecules to the surface of the film. ]]></text>
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     <text><![CDATA[At this stage the shape of the solvent molecules becomes more important than the chemical nature of solvent and resin. Moreover, if the thickness of the film is doubled the solvent retention time is quadrupled.]]></text>
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     <text><![CDATA[In any solvent blend it is important that the last trace of solvent to evaporate should be a true solvent in order to avoid precipitation of the resin and to relieve stress within the film.]]></text>
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     <text><![CDATA[A true solvent will be retained longer by a polymer film and may, indeed, act as a solvent plasticiser before finally evaporating.]]></text>
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     <text><![CDATA[Hard resins retain solvents longer than soft resin films.]]></text>
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     <text><![CDATA[2.1.6  Solvent Balance]]></text>
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     <text><![CDATA[Balanced Solvents]]></text>
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     <text><![CDATA[A blend of solvents that maintains solvency for film formers throughout the process of evaporation is described as balanced.]]></text>
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     <text><![CDATA[Solutions exhibit non-ideal behavior and deviate from Raoult's law.]]></text>
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     <text><![CDATA[The shape of the solvent molecule is an important factor in determining its rate of release from polymer films.]]></text>
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     <text><![CDATA[Considerable research has been undertaken to assist in predicting the behavior of solvent mixtures and the selection of economical and efficient blends of solvents that will satisfy the application requirements of surface coatings.]]></text>
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		<p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">One of the tools for doing this is to apply a correction factor known as the activity coefficient ( </span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:14pt;font-weight:bold;font-style:normal;">ץ</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> ) to the concentrations of the solvent components. &nbsp;</span></p></body>
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     <text><![CDATA[Activity coefficients are determined largely by their chemical functional group and describe the extent to which intermolecular forces are broken.]]></text>
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     <text><![CDATA[Although considerably simplified, an acceptable degree of accuracy can be achieved by assuming that solvents behave as three distinct groups ? ]]></text>
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     <text><![CDATA[alcohols and glycol ethers in hydrocarbons and ketones/esters]]></text>
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     <text><![CDATA[Values of the activity coefficients for each of these three groups can be deduced from graphs of one group plotted against the other two groups, at different concentrations.]]></text>
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		<p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">The theory is that the relevant evaporation rate or RER of a solvent in a blend is given by the formula based on Raoult&rsquo;s law:	RER = RER</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:9pt;font-weight:bold;font-style:normal;"><sup>0</sup></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:9pt;font-weight:normal;font-style:normal;"> </span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">. </span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:14pt;font-weight:normal;font-style:normal;">ץ</span></p><p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">where RER</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:9pt;font-weight:bold;font-style:normal;"><sup>0</sup></span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> is the pure (not</span><span style="color:#FF0000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;"> </span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">relative) evaporation rate of the pure solvent&nbsp;</span></p></body>
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     <text><![CDATA[Knowing the proportion and evaporation rate for each solvent in a mixture, it is possible to calculate information such as the total initial evaporation rate, whether the blend is balanced and the composition of residual solvent mixture when some of it has evaporated.]]></text>
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     <text><![CDATA[Shell Chemicals publish Technical Bulletins containing the necessary graphs and information to perform these calculations.]]></text>
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     <text><![CDATA[Computer modelling can be performed to predict more accurately the characteristics of solvent blends with specific polymer film formers but this is a costly and time consuming exercise.]]></text>
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     <text><![CDATA[Solvent suppliers use this technique to provide information about their products but it is not otherwise generally available.]]></text>
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     <text><![CDATA[The formulator must still rely on acquired skills and knowledge to propose various solvent blends in the first place and this comes largely from experience.]]></text>
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     <text><![CDATA[Read Surface Coatings Vol 1, section 24.3.1.3]]></text>
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   <correctAnswer><![CDATA[B]]></correctAnswer>
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<html xmlns="http://www.w3.org/1999/xhtml">
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		<p style="text-align:left;text-indent:0pt;margin:0pt 0pt 0pt 0pt;"><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">Refer back to the graph on screen #30. The activity coefficient </span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:12pt;font-weight:normal;font-style:normal;">( </span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:14pt;font-weight:normal;font-style:normal;">ץ</span><span style="color:#000000;background-color:transparent;font-family:Arial;font-size:12pt;font-weight:normal;font-style:normal;"> )</span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:bold;font-style:normal;"> </span><span style="color:#000000;background-color:transparent;font-family:'Trebuchet MS';font-size:14pt;font-weight:normal;font-style:normal;">for a hydrocarbon solvent in a blend with alcohol/glycol ethers at 40% concentration is: &nbsp;</span></p></body>
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]]></html>
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     <text><![CDATA[Please click on the correct button.]]></text>
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     <text><![CDATA[1.7<br/><br/><br/>2.0<br/><br/><br/>1.5]]></text>
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      <text><![CDATA[Correct. <br/><br/>]]></text>
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   <correctAnswer><![CDATA[D]]></correctAnswer>
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     <text><![CDATA[Self-assessment]]></text>
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     <text><![CDATA[If a solvent blend is unbalanced, it could result in:]]></text>
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     <text><![CDATA[Please click on the correct button.]]></text>
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     <text><![CDATA[Precipitation of the film former<br/>]]></text>
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     <text><![CDATA[A blend of solvents that maintains solvency for film formers throughout the process of evaporation is described as balanced.]]></text>
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     <text><![CDATA[Considerable research has been undertaken to assist in predicting the behavior of solvent mixtures and the selection of economical and efficient blends of solvents that will satisfy the application requirements of surface coatings. ]]></text>
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<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">The theory is that the relevant evaporation rate or RER of a solvent in a blend is given by the formula based on Raoult&rsquo;s law:  </span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">                    RER = RER</span><span style="font-family:'Trebuchet MS';font-size:9pt;"><b><sup>0</SUP></b></span><span style="font-family:'Trebuchet MS';font-size:14pt;">.</span><span style="font-family:'Arial';font-size:16pt;">&#1509;</span><span style="font-family:'Trebuchet MS';font-size:14pt;"> </span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">                                                               &nbsp;</span></p></body>]]></html>
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<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">where RER</span><span style="font-family:'Trebuchet MS';font-size:9pt;"><b><sup>0</SUP></b></span><span style="font-family:'Trebuchet MS';font-size:14pt;"> is the (pure) not relative evaporation rate of the pure solvent.</span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">                                                               &nbsp;</span></p></body>]]></html>
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     <text><![CDATA[Knowing the proportion and evaporation rate for each solvent in a mixture, it is possible to calculate information such as the total initial evaporation rate, whether the blend is balanced and the composition of residual solvent mixture when some of it has evaporated. ]]></text>
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     <text><![CDATA[We often describe solutions in terms of one substance dissolving another - the solute dissolves in the solvent.]]></text>
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     <text><![CDATA[Usually there is much more solvent than solute and the solubility of a substance is the maximum amount that can dissolve in a fixed amount of solvent to form a stable solution at a specified temperature.]]></text>
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     <text><![CDATA[Concentration is the amount of solute dissolved in a solution and expressed in terms of how much substance is present in a given mass or volume of the solution.]]></text>
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     <text><![CDATA[However, in most situations relating to film formers, the substances are miscible in any proportion with the solvent and the term solvent simply refers to the fact that it will evaporate after application and leave the film former behind. ]]></text>
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     <text><![CDATA[Concentration is simply a measure of the amount of film forming solids present in the solution.]]></text>
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     <text><![CDATA[It is unusual for a single solvent to be used in a surface coating, not only for reasons of cost but to give balance to other characteristics such as evaporation rate and flow.]]></text>
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     <text><![CDATA[There are four types of solvent used according to their behavior. ]]></text>
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     <text><![CDATA[They are true or active solvents, latent solvents, diluents and thinners. Thinners are often a blend of the first three.]]></text>
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     <text><![CDATA[There are two main types of solvent, hydrocarbons and oxygenated compounds.]]></text>
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     <text><![CDATA[In general there is a steady progression from paraffin through naphthenes to aromatics but hydrocarbons have low to medium solvency and dissolve only some of the resins, such as alkyds, used in surface coatings.]]></text>
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     <text><![CDATA[For example, boiling point increases as you go from paraffin to naphthene to aromatics. ]]></text>
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     <text><![CDATA[However, molecular weight decreases as you go from paraffin to naphthene to aromatic.]]></text>
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     <text><![CDATA[Oxygenated solvents contain oxygen in addition to carbon and hydrogen. The manner in which oxygen is bound within the molecule determines the physical and chemical properties of the solvent and hence its classification.]]></text>
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     <text><![CDATA[A wide range of oxygenated solvents is used in coatings, including ketones, esters, alcohols, glycol ethers and glycol ether acetates.]]></text>
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     <text><![CDATA[Oxygenated solvents in general are more powerful solvents than hydrocarbons and are mostly used in industrial coatings. ]]></text>
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     <text><![CDATA[They have strong odours, although not always unpleasant, and are generally more expensive than hydrocarbons.]]></text>
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     <text><![CDATA[Considerations when selecting a solvent include: cost, solvent power, volatility, toxicity, odour, flammability/flash point, viscosity, colour, water content, surface tension, contaminants, environmental or legislative requirements.]]></text>
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     <text><![CDATA[Kauri Butanol value and Aniline Point are methods of assessing the comparative solvent power of hydrocarbon solvents.]]></text>
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     <text><![CDATA[The flashpoint of a liquid may be defined as the lowest temperature at which the liquid, in contact with air, is capable of being ignited by a spark or flame under specified conditions.]]></text>
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     <text><![CDATA[The surface tension of a solvent is a measure of how well it will wet a surface and it is also a measure of its capillarity or capillary action.]]></text>
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     <text><![CDATA[The relative evaporation rate of solvents or diluents can be determined by measuring their loss in weight or volume as a function of time.]]></text>
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     <text><![CDATA[Towards the end of evaporation, when the solution is very highly viscous or solid and one of solvent in resin, the evaporation rate is controlled by diffusion of solvent molecules to the surface of the film. ]]></text>
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     <text><![CDATA[At this stage the shape of the solvent molecules becomes more important than the chemical nature of solvent and resin. Moreover, if the thickness of the film is doubled the solvent retention time is quadrupled.]]></text>
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     <text><![CDATA[In any solvent blend it is important that the last trace of solvent to evaporate should be a true solvent in order to avoid precipitation of the resin and to relieve stress within the film.]]></text>
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     <text><![CDATA[A true solvent will be retained longer by a polymer film and may, indeed, act as a solvent plasticiser before finally evaporating.]]></text>
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     <text><![CDATA[Hard resins retain solvents longer than soft resin films.]]></text>
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     <text><![CDATA[A blend of solvents that maintains solvency for film formers throughout the process of evaporation is described as balanced.]]></text>
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     <text><![CDATA[Considerable research has been undertaken to assist in predicting the behavior of solvent mixtures and the selection of economical and efficient blends of solvents that will satisfy the application requirements of surface coatings. ]]></text>
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<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">One of the tools for doing this is to apply a correction factor known as the activity coefficient ( </span><span style="font-family:'Arial';font-size:14pt;"><b>&#1509;</b></span><span style="font-family:'Trebuchet MS';font-size:14pt;"> ) to the concentrations of the solvent components. &nbsp;</span></p></body>]]></html>
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     <text><![CDATA[Activity coefficients are determined largely by their chemical functional group and describe the extent to which intermolecular forces are broken. ]]></text>
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<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">The theory is that the relevant evaporation rate or RER of a solvent in a blend is given by the formula based on Raoult&rsquo;s law:  </span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">                  RER = RER</span><span style="font-family:'Trebuchet MS';font-size:9pt;"><b><sup>0</SUP></b></span><span style="font-family:'Trebuchet MS';font-size:14pt;">.</span><span style="font-family:'Arial';font-size:16pt;">&#1509;</span><span style="font-family:'Trebuchet MS';font-size:14pt;"> </span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">                                                               &nbsp;</span></p></body>]]></html>
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<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">where RER</span><span style="font-family:'Trebuchet MS';font-size:9pt;"><b><sup>0</SUP></b></span><span style="font-family:'Trebuchet MS';font-size:14pt;"> is the (pure) not relative evaporation rate of the pure solvent.</span></p>
<p style='margin-top:0pt;margin-bottom:0pt;'><span style="font-family:'Trebuchet MS';font-size:14pt;">                                                               &nbsp;</span></p></body>]]></html>
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     <text><![CDATA[Knowing the proportion and evaporation rate for each solvent in a mixture, it is possible to calculate information such as the total initial evaporation rate, whether the blend is balanced and the composition of residual solvent mixture when some of it has evaporated. ]]></text>
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